TOC Front Cover 2 Extraction Chromatography 5 Copyright Page 6 Contributors 7 Preface 9 Contents 11 Chapter 1. Theoretical Aspects Of Extraction Chromatography 21 1. General comments 21 2. The influence of the support on the thermodynamic activities of the extractant and extracted complex 23 3. Main factors influencing the distribution coefficient and selectivity 26 4. Dynamic factors in extraction chromatography 30 Chapter 2. Correlation Between Extraction Chromatography And Liquid-Liquid Extraction 37 1. Theoretical correlation between liquid-liquid extraction and extraction chromatography 37 2. General considerations on the comparison of liquid-liquid extraction and extraction chromatographic results 40 3. Similarities in the practice of liquid-liquid extraction and extraction chromatography in each type of extraction system 43 Front Cover 2 Extraction Chromatography 5 Copyright Page 6 Contributors 7 Preface 9 Contents 11 Chapter 1. Theoretical Aspects Of Extraction Chromatography 21 1. General comments 21 2. The influence of the support on the thermodynamic activities of the extractant and extracted complex 23 3. Main factors influencing the distribution coefficient and selectivity 26 4. Dynamic factors in extraction chromatography 30 Chapter 2. Correlation Between Extraction Chromatography And Liquid-Liquid Extraction 37 1. Theoretical correlation between liquid-liquid extraction and extraction chromatography 37 2. General considerations on the comparison of liquid-liquid extraction and extraction chromatographic results 40 3. Similarities in the practice of liquid-liquid extraction and extraction chromatography in each type of extraction system 43 4. Concluding remarks 61 Chapter 3. Techniques In Column Extraction Chromatography 65 Introduction 65 1. Standardization of support material 66 2. Loading of the support material with stationary phase 70 3. Bed dimensions, column types and column packing procedures 72 4. Determination of column parameters 76 5. Working techniques in operating extraction chromatographic columns 79 6. Detection methods 86 Chapter 4. Stationary Phases In Extraction Chromatography 88 1. General performances of stationary phases 89 Introduction 89 2. Systematic survey of the extractants used as stationary phases 102 Chapter 5. Inert Supports In Column Extraction Chromatography 154 1. Requirements for supports in partition chromatography 154 2. Materials used for supports 155 3. The influence of the structure and size of the support particles on the efficiency of chromatographic columns 170 4. Properties of the different supports 171 5. Loading of the stationary phase on the supports. Regeneration of supports 186 6. Supports for preparative and continuous chromatography 187 Chapter 6. Extraction Chromatography Of Metallic And Non-Metallic Ions 195 Introduction 195 1. Radiochemical separations and production of carrier-free radioisotopes. The separation of mother-daughter pairs 196 2. The separation of alkali and alkaline earth metals 200 4. The separation of aluminium group metals 202 3. The separation of I B and IIB sub-group elements 202 5. The separation of IVB sub-group elements 203 6. The separation of chromium sub-group elements 204 7. The separation of iron sub-group elements 205 8. The separation of noble metals 206 9. The separation of halide ions 207 10. The separation of other ions 207 Chapter 7. Extraction Chromatography Of Actinides 211 1. Introduction 211 2. Liquid-liquid extraction of actinides 213 3. Extraction chromatography of actinides 217 4. Examples of actinide separations by extraction chromatography 221 Chapter 8. Extraction Chromatography Of Lanthanides 246 Introduction 246 1. Extraction of lanthanides 247 2. The double-double effect and its significance for the lanthanide and actinide separation 253 3. The enthalpies of lanthanide extraction and the influence of temperature on the separation factor 258 4. Survey of the lanthanide separations 261 5 . Resolution ability of columns used for the separation of lanthanides 268 Chapter 9. Extraction Chromatography Of Fission Products 274 1. Introduction 274 2. Separation systems and procedures 275 3. Reprocessing analysis 280 4. Burn-up Analysis 289 5. Fission products in nuclear chemistry 293 6. Commercial fission product recovery 296 Chapter 10. Use Of Extraction Chromatography In Radiotoxicology 299 1. General remarks 300 2. Analytical procedures 305 3. Conclusions 320 Chapter 11. Chelating Agents As Stationary Phase In Extraction Chromatography 324 1. Introduction 324 2. Theory of extraction by chelating agents 325 3. Experimental technique 332 4. Chelating agents and systems used 334 Chapter 12. Use Of Extraction Chromatography For Trace Metal Preconcentration And Separation 345 1. Introduction 345 2. Experimental techniques 346 3. Individual and collective preconcentration and separation of trace impurities 349 4. Effects of certain factors on the preconcentration and separation of elements by column extraction chromatography 353 5. Conclusions 362 Chapter 13. Use Of Cellular Plastics In Extraction Chromatography 364 I. Introduction 364 2. Cellular plastics as extraction chromatographic supports 365 3. The application of foam-filled columns in some inorganic and radiochemical separations 369 Chapter 14. Laminar Techniques As An Aid In Planning Column Extraction Chromatographic Separations 386 1. Introduction 386 2. Experimental techniques in laminar extraction chromatography 387 3. Correlation between Rf values and distribution coefficients 389 4. Correlation between Rf values and retention volumes 392 5. Planning column separations from laminar results 396 6. Literature survey of available Rf spectra 401 7. Conclusions 418 Chapter 15. Bibliography Of Extraction Chromatography 422 1. Introduction 422 2. Selection of papers 424 3. Bibliographies 425 4. Reviews and books 425 5. Original publications on laminar extraction chromatography 429 6. Original publications on column extraction chromatography 447 7. Tabular survey of experimental data on column extraction chromatographic investigations 501 8. Stationary phases used in column extraction chromatography 551 9. Support materials used in column extraction chromatography 557 10. Author index 561 11. Corporate author index 568 Subject Index 577 Show more