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Organophosphorus Chemistry

From Molecules to Applications

Authors: Viktor Iaroshenko Publisher: Wiley Publication date: 2019 Publication language: Angielski Number of pages: 589 Publication formats: EAN: 9783527672257 ISBN: 9783527672257 Category: Chemistry Publisher's index: - Bibliographic note: -

Description

Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented.

For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.

TOC

  • Cover 2
  • Title Page 6
  • Copyright 7
  • Contents 8
  • Chapter 1 Phosphines and Related Tervalent Phosphorus Systems 18
    • 1.1 Introduction 18
      • 1.1.1 History 18
      • 1.1.3 Aim of the Chapter 19
      • 1.1.2 Alternative Ligands 19
    • 1.2 Synthesis of Phosphorus Ligands 20
      • 1.2.2 Nucleophilic Substitution by Carbanions at Pδ+ 20
      • 1.2.1 Introduction 20
      • 1.2.3 Phosphorus–Carbon Bond Cleavage and Phosphido Anion Preparation 24
      • 1.2.4 Phosphido Anions as Nucleophiles 26
      • 1.2.5 P─H Addition to Unsaturates 29
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